Podrobnosti záznamu

Název
    Determination of Total Sulfur in Fifteen Geological Materials Using Inductively Coupled Plasma-Optical Emission Spectrometry (ICP-OES) and Combustion/Infrared Spectrometry
Autor
    Ackerman, Lukáš
    Rohovec, Jan
    Šebek, O.
Jazyk
    anglicky
Typ dokumentu
    článek v odborném periodiku
Zdrojový dokument - seriál
    Geostandards and Geoanalytical Research
Svazek/č.
    Roč. 36, č. 4
Strany
    s. 407-414
Rok
    2012
Poznámky
    Projekt: KJB300130612, GA AV ČR3cav_un_auth*0217163
    Rozsah: 8 s. : WWW
    Výzkumný záměr: CEZ:AV0Z30130516
Předmětová kategorie
    combustion
    ICP-OES
    infrared detection
    reference materials
    sulfur
Klíčové slovo
    Combustion/Infrared
    Coupled
    Determination
    Emission
    Fifteen
    Geological
    ICP-OES
    Inductively
    Materials
    Plasma-Optical
    Spectrometry
    Sulfur
    Total
    Using
Abstrakt (anglicky)
   A method for the determination of total sulfur in geological materials by inductively coupled plasma-optical emission spectrometry (ICP-OES) is described. We show that good results were obtained using this method even for sample types with very low (< 20 μg g−1) sulfur concentration (e.g., peridotite). Sulfur was determined in fifteen geological reference materials with different sulfur contents. For reference materials with certified sulfur contents, the ICP-OES method gave results in excellent agreement with certified values, and uncertainties better than 4% RSD. ICP-OES results for sulfur in other reference materials yielded RSDs better than 10%, where S concentrations were > 100 μg g−1 (except for diabase W-2a, 16% RSD). Reference materials with lower sulfur contents (< 40 μg g−1) showed much higher RSDs (17-18%).
   Except for RMs with certified values for sulfur, most data obtained by the combustion infrared detection method generally showed higher concentrations than those measured by ICP-OES and a better RSD (≤ 8% for all materials except DTS-2b).
Přispěvatel
    AV ČR Brno, Geologický ústav
Kód přispěvatele
    AV ČR, GLÚ
Zdrojový formát
    U
Datum importu
    19. 3. 2014